Ethylation of ethyl phenylphosphinate (I)via ethyl trimethylsilyl phenylphosphonite or via the corresponding trimethylstannyl ester, and free-radical addition of (I) to ethylene proceed with complete, or almost complete, retention of configuration.
G. R. van den Berg, D. H. J. M. Platenburg and H. P. Benschop, J. Chem. Soc. D, 1971, 606 DOI: 10.1039/C29710000606
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