Optically active (1-methylheptyl)bis(dimethyl-glyoximinato)pyridine-cobalt(III) and -rhodium(III) have been prepared from (–)-1-methylheptyl bromide; cleave age of the organocobalt compound with bromine regenerates (–)-1-methylheptyl bromide of greater than 50% optical purity.
D. Dodd and M. D. Johnson, J. Chem. Soc. D, 1971, 571 DOI: 10.1039/C29710000571
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