A new method for converting quinone Diels–Alder adducts into cyclohexadiene derivatives is used for the synthesis of tricyclo[4,4,0,02,5]deca-3,7,9-triene, which rearranges to tricyclo[4,2,2,02,5]deca-3,7,9-triene at 70°.
E. Vedejs, J. Chem. Soc. D, 1971, 536 DOI: 10.1039/C29710000536
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