Issue 10, 1971

An oxidation-reduction reaction, not directly related to electrolysis, brought about by the application of a DC potential across a single crystal of the partially oxidised platinum atom chain compound K2Pt(CN)4Br0.3,2·5H2O

Abstract

The application of a DC potential (>150 V cm–1) across single crystals of the partially oxidised platinum atom chain compound K2Pt(CN)4Br0·3,2·5H2O induces a oxidation–reduction which commences at the anode and spreads through the crystal to the cathode; the product of the reaction is K2Pt(CN)4,2H2O in a polycrystalline form.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 511-512

An oxidation-reduction reaction, not directly related to electrolysis, brought about by the application of a DC potential across a single crystal of the partially oxidised platinum atom chain compound K2Pt(CN)4Br0.3,2·5H2O

P. S. Gomm and A. E. Underhill, J. Chem. Soc. D, 1971, 511 DOI: 10.1039/C29710000511

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