The mechanism of the catalytic decomposition of methanol on gold has been investigated using deuteriated methanol; the primary products of CH3OD decomposition are CHDO and H2 and further reaction leads to mainly HCHO, HD, and CO.
J. G. Hardy and M. W. Roberts, J. Chem. Soc. D, 1971, 494 DOI: 10.1039/C29710000494
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