Issue 7, 1971

Effect of stabilizing substituents on [2,3] sigmatropic rearrangements of sulphonium ylides

Abstract

The sulphonium salt (VII) when exposed to base is cleanly rearranged to the sulphide (IX) even at –40°, indicating that extensive delocalisation of the intermediate ylide is insufficient to prevent the sigmatropic rearrangement.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 359-359

Effect of stabilizing substituents on [2,3] sigmatropic rearrangements of sulphonium ylides

J. E. Baldwin and W. F. Erickson, J. Chem. Soc. D, 1971, 359 DOI: 10.1039/C29710000359

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements