Dithiochloroformates react with metal sulphinates to give trithiocarbonate SS-dioxides (I), and phenyl dithiochloroformate and sodium methanesulphinate give phenyl (phenylthio)(methylsulphonyl)methyl disulphide (II); towards nucleophiles, the dioxides (I) behave as thioacylating agents.
N. H. Nilsson, C. Jacobsen and A. Senning, J. Chem. Soc. D, 1971, 314 DOI: 10.1039/C29710000314
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