The relative Raman intensities and the depolarisation behaviour for the A1 and Eν(CO) modes in C6H6Cr(CO)3 and C5H5Mn(CO)3 differ considerably; this observation is interpreted in terms of a bond-derived polarisability model.
S. F. A. Kettle, I. Paul and P. J. Stamper, J. Chem. Soc. D, 1971, 235 DOI: 10.1039/C29710000235
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