Issue 5, 1971
From the journal:

Journal of the Chemical Society D: Chemical Communications

Transition-metal complexes with (CF3)2C[double bond, length as m-dash]N– as ligand and a tautomeric hydrogen transfer from metal to ligand

B. Cetinkaya,   M. F. Lappert  and  J. McMeeking  

Abstract

Reactions of appropriate metal chlorides and (CF3)2C[double bond, length as m-dash]NLi (RLi) afford the novel ketimides (π-C5H5)2Ti(R)Cl, (Ph3P)3RhR, cis-(Ph3P)2Pt(R)Cl, trans-(Ph3P)2Pt(R)H, cis-(Me2PhP)2Pt(R)Cl, cis-(Me2PhP)2PtR2, and trans-(Me2PhP)2Pt(R)H; and trans-(Ph3P)2Pt-(R)H is isomerised by heating with Ph3P in benzene to yield (Ph3P)2Pt[HNC(CF3)2].

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Article information

DOI
https://doi.org/10.1039/C29710000215
Article type
Paper

J. Chem. Soc. D, 1971, 215-216

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Transition-metal complexes with (CF3)2C[double bond, length as m-dash]N– as ligand and a tautomeric hydrogen transfer from metal to ligand

B. Cetinkaya, M. F. Lappert and J. McMeeking, J. Chem. Soc. D, 1971, 215 DOI: 10.1039/C29710000215

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