The vanadium atom in bis-(2-methyl-8-quinolinolato)oxovanadium(IV) is five-co-ordinate and has a trigonal-bipyramidal co-ordinate and has a trigonal-bipyramidal co-ordination polyhedron in which the three oxygen atoms and the vanadium atom are in the equatorial plane and the two nitrogen donors occupy the apical positions.
M. Shiro and Q. Fernando, J. Chem. Soc. D, 1971, 63 DOI: 10.1039/C29710000063
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