The Photo-electron spectra of silyl and germyl chlorides provide evidence that (p→d)π-bonding does occur between Cl and Si or Ge; the spectra of the bromides and iodides are less conclusive.
S. Cradock and E. A. V. Ebsworth, J. Chem. Soc. D, 1971, 57 DOI: 10.1039/C29710000057
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