Among the ions present in the ion cyclotron resonance spectrum of a mixture of butane-2,3-dione and ethanol at low ionizing voltage is a species of m/e 115 which is shown by deuterium labelling to correspond to a product of dehydration of the mixed-solvate (CH3COCOCH3)(C2H5OH)H+ in which both hydrogen atoms lost originate from the hydroxy-group of ethanol.
T. A. Lehman, T. A. Elwood, M. K. Hoffman and M. M. Bursey, J. Chem. Soc. B, 1970, 1717 DOI: 10.1039/J29700001717
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