Raman spectra have been obtained for molten and solid Ga2Cl4 and mixtures with Ga2Cl6 in which the compound Ga3Cl7 is formed. It is shown that Ga3Cl7 and KGa2Cl7 have the constitution M+Ga2Cl7– in the solid state. Solutions of gallium in molten Ga2Cl4 give, in addition to the GaCl4– spectrum, an extra Raman band at 235 cm–1, close to the most intense band of Ga2Cl62–.
M. J. Taylor, J. Chem. Soc. A, 1970, 2812 DOI: 10.1039/J19700002812
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...