Mössbauer parameters have been measured for a series of diorganotin bisdithiocarbamates and interpreted in terms of cis-octahedral structures for Ph2Sn[S2CNR2]2 and trans-octahedral structures for R12Sn[S2CNR22]2. Factors affecting the stereochemistry of organotin hexaco-ordinate complexes are discussed.
B. W. Fitzsimmons, A. A. Owusu, N. J. Seeley and A. W. Smith, J. Chem. Soc. A, 1970, 935 DOI: 10.1039/J19700000935
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