SCHEDULED MAINTENANCE
Mössbauer spectra for a wide range of tetraorganotin compounds of the general types Me3SnX, (Me3Sn)2X, and Me2SnX2(where X is an aryl group with other substituents) have been obtained. The observed quadrupole splittings show a marked dependence on the nature of ortho-substituents. The splittings are apparently induced by asymmetry in the σ-bonding.
T. Chivers and J. R. Sams, J. Chem. Soc. A, 1970, 928 DOI: 10.1039/J19700000928
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