Issue 0, 1970
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


The nuclear magnetic resonance spectra of some platinum and palladium π-allyl complexes and their reactions with sulphur dioxide

S. O'Brien  

Abstract

The 1H n.m.r. spectrum of Pt(2-methylallyl)2 has been examined and that of Pt(allyl)2 re-examined at 220 MHz. The spectra indicate that both compounds exist in solution in two isomeric forms with symetrically bonded π-allyl ligands. Pd(allyl)2 reacts with sulphur dioxide to form (C3H5) Pd(SO2C3H5) in which the sulphur dioxide has inserted into only one of the π-allyl ligands. The n.m.r. and i.r. spectra of this compound are discussed.

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Article information

DOI
https://doi.org/10.1039/J19700000009
Article type
Paper

J. Chem. Soc. A, 1970, 9-13

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The nuclear magnetic resonance spectra of some platinum and palladium π-allyl complexes and their reactions with sulphur dioxide

S. O'Brien, J. Chem. Soc. A, 1970, 9 DOI: 10.1039/J19700000009

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