Field ionisation mass spectrometry of substituted aryl O-glucosides demonstrates that cleavage and rearrangement reactions occur at the glucosidic bond, and using the Hammett relationship log Z/Z0=ρσ may be correlated to give ρ+ 0·7 for rearrangement and ρ+ 2·0 for cleavage.
G. O. Phillips, W. G. Filby and W. L. Mead, J. Chem. Soc. D, 1970, 1269b DOI: 10.1039/C2970001269B
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