Issue 14, 1970

Photoelectron spectra of transition-metal hexafluoroacetylacetonates and the supposed breakdown of Koopmans' theorem in these compounds

Abstract

The initial parts of the photoelectron spectra of the trishexafluoroacetylacetone complexes of chromium, iron, and cobalt are presented; from the spectra there is no evidence for any inversion of orbital sequence upon ionization, but the chromium and iron complexes show an effect which may be ascribed to their open-shell nature.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 868b-870

Photoelectron spectra of transition-metal hexafluoroacetylacetonates and the supposed breakdown of Koopmans' theorem in these compounds

D. R. Lloyd, J. Chem. Soc. D, 1970, 868b DOI: 10.1039/C2970000868B

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