A new series of high molecular weight poly(diaminophosphazenes), [NP(NEt2)(NR2)]n or [NP(NEt2)(NHR)]n, has been prepared by the interaction of poly(dichlorophosphazene) with diethylamine, followed by treatment with a second amine: the polymers are stable, transparent, flexible or elastomeric materials.
H. R. Allcock and D. P. Mack, J. Chem. Soc. D, 1970, 685a DOI: 10.1039/C2970000685A
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