Issue 8, 1970

Formation of a Meisenheimer salt from a substituted picramide and potassium methoxide in methanol; the isolation of a neutral Meisenheimer complex

Abstract

The substituted picramide (III) gives the 1-σ(Meisenheimer) complex (IV) on treatment with KOMe in methanol; when an equivalent of HCl is added to (IV) the relatively stable neutral complex (V) is produced, which decomposes to (III) and methanol in polar solvents.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 511b-512

Formation of a Meisenheimer salt from a substituted picramide and potassium methoxide in methanol; the isolation of a neutral Meisenheimer complex

E. Bergman, N. R. McFarlane and J. J. K. Boulton, J. Chem. Soc. D, 1970, 511b DOI: 10.1039/C2970000511B

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