Acyl halides react with triethylsilane in presence of certain platinum complexes to give aldhydes, but in the presence of rhodium catalysts (e.g. mer-[RhCl3(PBun2-Ph)3]) formation of ketones can predominate.
S. P. Dent, C. Eaborn and A. Pidcock, J. Chem. Soc. D, 1970, 1703 DOI: 10.1039/C29700001703
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