In contrast with the reactions of NiL4(L = tertiary phosphine), Ni(ButNC)4 reacts with (CF3)2CO and (CF3)2CNH to give five-membered-ring compounds (ButNC)2[graphic omitted](X = O or NH) in an almost stereoselective 3- to 5-ring transformation.
A. Greco, M. Green, S. K. Shakshooki and F. G. A. Stone, J. Chem. Soc. D, 1970, 1374 DOI: 10.1039/C29700001374
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