In the compound [N6P6(NMe2)12CuCl]+CuCl2–, a 5-co-ordinated cupric ion is situated inside the 12-membered ring, the slight weakening of the ring bonds to the co-ordinating nitrogen atoms being partially compensated by increased electron release.
W. C. Marsh, N. L. Paddock, C. J. Stewart and J. Trotter, J. Chem. Soc. D, 1970, 1190 DOI: 10.1039/C29700001190
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