In cis- and trans-dichloro[CH:CH·(CH2)n·[graphic omitted]H(Me)Et](benzylamine)platinum(II) complexes, the asymmetric carbon atom originally present in the olefin induces the opposite absolute configuration in the tertiary carbon atom bound to Pt and, at least in the cis-complexes, the extent of asymmetric induction rapidly diminishes with increasing n.
R. Lazzaroni, P. Salvadori and P. Pino, J. Chem. Soc. D, 1970, 1164 DOI: 10.1039/C29700001164
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