CoIII–SCN bonds can be formed in the presence of suitable ligands but, for some ligands, isomerisation occurs in solution to give a mixture of linkage isomers: in contrast to the behaviour observed for thiocyanatopalladium(II) complexes, M–NCS bond formation is promoted in solvents having high dielectric constants.
A. H. Norbury, P. E. Shaw and A. I. P. Sinha, J. Chem. Soc. D, 1970, 1080 DOI: 10.1039/C29700001080
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