Issue 16, 1970

Stereochemistry of the photoisomerisation of 4-methylenebicyclo[3,1,0]hex-2-enes to spiro[2,4]hepta-4,6-dienes

Abstract

The photochemical isomerisation of a 4-methylenebicyclo[3,1,0]hex-2-ene derivative to a spiro[2,4]hepta-4,6-diene proceeds with a high degree of stereospecificity and is interpreted in terms of an excited state sigmatropic 1,5-shift followed by a thermal 1,5-shift.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 1013-1014

Stereochemistry of the photoisomerisation of 4-methylenebicyclo[3,1,0]hex-2-enes to spiro[2,4]hepta-4,6-dienes

N. K. Hamer and M. Stubbs, J. Chem. Soc. D, 1970, 1013 DOI: 10.1039/C29700001013

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