γ-Diketones, obtained as by-products in the electrolytic cleavage of β-keto-sulphones at a mercury cathode, have been demonstrated to form via radical dimerization rather than nucleophilic displacement.
B. Lamm and B. Samuelsson, J. Chem. Soc. D, 1970, 1010 DOI: 10.1039/C29700001010
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