Carbon monoxide when bound to reduced cytochrome c oxidase of bovine heart has been found to exhibit one C–O stretch band with a frequency and band-width consistent with a terminal CO ligand bound to heme A iron within a non-polar environment well-isolated from external solvent.
W. S. Caughey, R. A. Bayne and S. McCoy, J. Chem. Soc. D, 1970, 950 DOI: 10.1039/C29700000950
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