Selenium tetrachloride is shown by gas-phase laser Raman spectroscopy to be fully dissociated in the vapour to selenium dichloride and chlorine, the vibrational spectrum of gaseous selenium dichloride being entirely consistent with that expected for a non-linear triatomic molecule.
G. A. Ozin and A. V. Voet, J. Chem. Soc. D, 1970, 896 DOI: 10.1039/C29700000896
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