The thermal rearrangement of tricarbonylmethylcycloheptatrienechromium is shown to follow a metal-assisted stereospecific pathway involving sequential 1,5-shifts of the 7-endo-hydrogen atom across the face of the ring adjacent to the metal atom.
M. I. Foreman, G. R. Knox, P. L. Pauson, K. H. Todd and W. E. Watts, J. Chem. Soc. D, 1970, 843 DOI: 10.1039/C29700000843
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