Acid-catalysed disproportionation of 1,2,3,4-tetrahydro-8-methoxy-6H-benzo[b,d]thiopyran gives two reduction products, both of which are derived from the intermediate bridgehead thiiranium ion.
E. R. de Waard, W. J. Vloon and H. O. Huisman, J. Chem. Soc. D, 1970, 841 DOI: 10.1039/C29700000841
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