Issue 13, 1970
From the journal:

Journal of the Chemical Society D: Chemical Communications

Chirality in transition-metal chemistry. The formation of diastereomers in the reaction of the stereoisomers of hexa-2,4-diene with palladium chloride

J. Lukas,   P. W. N. M. van Leeuwen,   H. C. Volger  and  P. Kramer  

Abstract

Diastereomeric pairs of enantiomers of 1-(1-chloroethyl)- 3-methyl-π-allylpalladium chloride are formed when either trans,trans-, cis,cis-, or ci,strans-hexa-2,4-diene are allowed to react with palladium chloride at –40° in an aprotic solvent: these reactions can be employed to effect the conversions, cis,cis→trans,trans⇄cis, trans-hexa-2,4-diene.

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Article information

DOI
https://doi.org/10.1039/C29700000799
Article type
Paper

J. Chem. Soc. D, 1970, 799-800

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Chirality in transition-metal chemistry. The formation of diastereomers in the reaction of the stereoisomers of hexa-2,4-diene with palladium chloride

J. Lukas, P. W. N. M. van Leeuwen, H. C. Volger and P. Kramer, J. Chem. Soc. D, 1970, 799 DOI: 10.1039/C29700000799

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