Using normal peptide coupling agents it has proved extremely difficult to prepare peptides of 3-amino-3-methylbutanoic acid; however aminolysis of the intermediate oxazinone proceeds smoothyl, yielding the required compounds.
J. Lowbridge and C. N. C. Drey, J. Chem. Soc. D, 1970, 791 DOI: 10.1039/C29700000791
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