Homogeneous and heterogeneous metal-catalysed isotopic hydrogen exchange in the alkyl group of [β-14C]ethylbenzene shows that predominant deuteriation does not occur via previously suggested mechanisms involving reversible dealkylation or carbonium ion intermediates: instead a π-allylic process is suggested.
J. L. Garnett and R. S. Kenyon, J. Chem. Soc. D, 1970, 698 DOI: 10.1039/C29700000698
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