The crystal structure of Fe(CO)4(HgCl·py)2 has been determined by X-ray diffraction analysis: the iron atom is octahedrally co-ordinated by four carbonyl groups and two mercury atoms but the co-ordination of the mercury atoms involving one iron atom, two chlorine atoms, one pyridine nitrogen atom, and a possible mercury–mercury bond is not simple.
R. W. Baker and P. Pauling, J. Chem. Soc. D, 1970, 573 DOI: 10.1039/C29700000573
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