The aminolysis of acetylimidazole by ethylene-diamine shows a rate enhancement of more than 103 compared to glycine, which is attributed to intramolecular general base catalysis; the reaction with acetylimidazolium ion shows no significant rate enhancement.
Wm. P. Jencks and K. Salvesen, J. Chem. Soc. D, 1970, 548 DOI: 10.1039/C29700000548
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