The microsymmetry about the cobalt atom in the title compound is almost exactly octahedral, and the ligand in the complex is not extensively conjugated; nevertheless, a “crossover” situation is shown to exist in this complex, and use of this phenomenon is made in the assignment of its metal–ligand vibrations.
P. F. B. Barnard, A. T. Chamberlain, G. C. Kulasingam, W. R. McWhinnie and R. J. Dosser, J. Chem. Soc. D, 1970, 520 DOI: 10.1039/C29700000520
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