m-Chloroperbenzoic acid and 3-acetoxy-androsta-3,5-dien-17-one form a 1:1 addition compound (III) in non-polar solvents, or 6β-hydroxyandrost-4-ene-3,17-dione (II) in aqueous solvents.
D. N. Kirk and J. M. Wiles, J. Chem. Soc. D, 1970, 518 DOI: 10.1039/C29700000518
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