A synchronous fragmentation reaction, with acceleration, has been observed in the acetolysis of the endo-toluene-p-sulphonate of the title compound: for the exo-toluene-p-sulphonate, although some fragmentation occurs, no rate acceleration was observed.
R. Baker, T. J. Mason and J. C. Salter, J. Chem. Soc. D, 1970, 509 DOI: 10.1039/C29700000509
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