The metal atom in the triclinic tin(II) phthalocyanine is 1·11 Å out of the plane of the four co-ordinating nitrogen atoms; the phthalocyanine moiety is significantly non-planar.
M. K. Friedel, B. F. Hoskins, R. L. Martin and S. A. Mason, J. Chem. Soc. D, 1970, 400 DOI: 10.1039/C29700000400
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