Issue 0, 1969
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


The iron(II)–chromium(VI) reaction: an additional pathway first order in iron(II)

D. R. Rosseinsky  and  M. J. Nicol  

Abstract

The iron(II)–chromium(VI) reaction has been studied by platinum-electrode polarography at low (micromolar) iron(II) concentrations. Here an additional term first order in iron(II) appears in the rate equation, which is found to be –d[FeII]/dt=k1H[H+][HCrO4–][FeII]+k2H[HCrO4–][FeII]2/[Fe3+], with k1H= 234 l2 mol–4 s–1 and 10–8k2H= 6·92 l4 mol–4 s–1 at 20 °C and ionic strength 1·00 mol l–1 in sodium perchlorate medium with 0·025–0·065M perchloric acid.

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Article information

DOI
https://doi.org/10.1039/J19690002887
Article type
Paper

J. Chem. Soc. A, 1969, 2887-2890

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The iron(II)–chromium(VI) reaction: an additional pathway first order in iron(II)

D. R. Rosseinsky and M. J. Nicol, J. Chem. Soc. A, 1969, 2887 DOI: 10.1039/J19690002887

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