Issue 0, 1969

Organosilicon and organotin phosphines and arsines as mono- and poly-dentate ligands to metal carbonyls

Abstract

The organometallic phosphines and arsines Me3SnPPh2, Me2Sn(PPh2)2, Me3SiAsMe2, Me2Si(AsMe2)2, MeSi(AsMe2)3, Me3SnAsMe2, and Me2Sn(AsMe2)2 react with nickel, chromium, and molybdenum carbonyls, behaving as mono-, bi-, and tri-dentate ligands as appropriate. The i.r. and 1H n.m.r. spectra of the products are reported and discussed.

Article information

Article type
Paper

J. Chem. Soc. A, 1969, 1631-1633

Organosilicon and organotin phosphines and arsines as mono- and poly-dentate ligands to metal carbonyls

E. W. Abel, J. P. Crow and S. M. Illingworth, J. Chem. Soc. A, 1969, 1631 DOI: 10.1039/J19690001631

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