Treatment of [Et4N][M(CO)5l] with RCH2NH2(R = Me, H) and Me2NH provides a good general method for the preparation of amine-metal carbonyls of formulae M(CO)5RCH2NHX (M = Cr, Mo, W; X = Me, H; R = Me, H). The 1H n.m.r. and i.r. spectra of these new amine complexes are discussed in relation to some comparable phosphine derivatives.
B. W. Cook, R. Jackson, R. G. J. Miller and D. T. Thompson, J. Chem. Soc. A, 1969, 25 DOI: 10.1039/J19690000025
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