The conformation of an aromatic disulphide linkage is best described by two torsion angles: the one involving the C–S–S–C atoms (usually near 90°) and that relating the orientation of the S–S bond to the plane of the phenyl ring (either ca. 0° or ca. 90°).
E. Shefter and T. I. Kalman, J. Chem. Soc. D, 1969, 1027b DOI: 10.1039/C2969001027B
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