1 H n.m.r. emission at both α- and β-positions in Stevens rearrangement products, but not eliminated olefins, from quaternary ammonium intermediates is indicative of caged radical pairs in the migration process.
A. R. Lepley, J. Chem. Soc. D, 1969, 1460 DOI: 10.1039/C29690001460
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