1,2,2-Trifluoroethylidene readily inserts into the Si–H bond of trialkylsilanes, but insertion into the Si–Cl bonds of silicon tetrachloride or methylchlorosilanes is more difficult; with certain silanes containing Si–H and Si–Cl bonds both types of insertion take place.
R. N. Haszeldine, A. E. Tipping and R. O'B. Watts, J. Chem. Soc. D, 1969, 1364 DOI: 10.1039/C29690001364
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