Rotational barriers exist about the N–aryl bond of p′-substituted p-dimethylaminophenyldiphenylmethyl cations; these kinetic barriers are substituent dependent and relate directly to π-charge delocalization energies independently determined from thermodynamic data.
J. W. Rakshys, S. V. McKinley and H. H. Freedman, J. Chem. Soc. D, 1969, 1180 DOI: 10.1039/C29690001180
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