Secondary α-ketol acetates in the presence of acetic acid–acetate ion or acetic acid alone undergo two reactions: (a) interchange of the functional groups at ca. 150° and (b) transfer of the acetate from the α-to the α′-position of the ketone at ca. 220°.
I. S.-Y. Wang and E. W. Warnhoff, J. Chem. Soc. D, 1969, 1158 DOI: 10.1039/C29690001158
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