The reaction between π-C5H5(OC)3M–H (M = Mo or W) and Me3SiCHN2 provides the first example of a 1,3-organometallic insertion and the products π-C5H5(OC)2M·N![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
N·CH2SiMe3 are the first stable alkylazo-compounds.
M. F. Lappert and J. S. Poland, J. Chem. Soc. D, 1969, 1061 DOI: 10.1039/C29690001061
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