Calculation of an ab-initio wavefunction for the ground state of bis-(π-allyl)nickel indicates that most of the bonding between the nickel atom and the ligands involves the 4s- and 4p-orbitals of the metal.
A. Veillard, J. Chem. Soc. D, 1969, 1022 DOI: 10.1039/C29690001022
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